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讲师 

Bai Ruopeng

Ph. D.

Assistant Professor

联系方式

LC220, College of Chemistry and Chemical Engineering, Huxi Campus, Chongqing University, 401331

研究方向

Theory directed mechanism investigation of transition metal catalyzed coupling reactions

Transition metal catalyzed hydrotransition reactions

Bulky ligand design and application

代表性论文、专著和专利

“Ni(I)–Ni(III) vs Ni(II)–Ni(IV): Mechanistic Study of Ni-catalyzed Alkylation of Benzamides with Alkyl Halides.” Li, Yingzi; Yu, Da-Gang*; Bai, Ruopeng*; Lan, Yu*, Organic Chemistry Frontiers 2018, 5, 615-622.

 

“On the Mechanism of Copper-Catalyzed Oxytrifluoromethylation of Allylamines with CO2: A Computational Study.” Zhu, Lei; Ye, Jian-Heng; Duan, Meng; Qi, Xiaotian; Zou, Lufeng; Bai, Ruopeng*; Lan, Yu*, Organic Chemistry Frontiers 2018, 5, 633-639.

 

“Ni-Catalyzed C–F Bond Functionalization of Unactivated Aryl Fluorides and Corresponding Coupling with Oxazoles.” Yin, Youzhi; Yue, Xiaoyu; Zhong, Qi; Jiang, Hanmin; Bai, Ruopeng*; Lan, Yu*; Zhang Hua*, Advanced Synthesis & Catalysis 2018, 5, DOI: 10.1002/adsc.201701506.

 

“C–H bond cleavage occurring on a Rh(V) intermediate: a theoretical study of Rh-catalyzed arene azidation.” Liu, Song; Qi, Xiaotian; Qu, Ling-Bo; Bai, Ruopeng*; Lan, Yu*, Catalysis Science & Technology 2018, 5, DOI: 10.1002/adsc.201701506.

 

“Insights into disilylation and distannation: sequence influence and ligand/steric effects on Pd-catalyzed difunctionalization of carbenes.” Yue, Xiaoyu; Shan, Chunhui; Qi, Xiaotian; Luo, Xiaoling; Zhu, Lei; Zhang, Tao; Li, Yuanyuan; Li, Yingzi; Bai, Ruopeng*; Lan, Yu*, Dalton Transactions 2018, 47, 1819-1826.

 

 “Mechanism of Rhodium-Catalyzed C–H Functionalization: Advances in Theoretical Investigation.” Qi, Xiaotian; Li, Yingzi; Bai, Ruopeng; Lan, Yu*, Accounts of Chemical Research 2017, 50, 2799–2808.

 

“From Mechanistic Study to Chiral Catalyst Optimization: Theoretical Insight into Binaphthophosphepine-catalyzed Asymmetric Intramolecular [3+2] Cycloaddition.” Duan, Meng; Zhu, Lei; Qi, Xiaotian; Yu, Zhaoyuan; Li, Yingzi; Bai, Ruopeng*; Lan, Yu*, Scientific Reports 2017, 7, 7619.

 

“Stabilization of Two Radicals with One Metal: A Stepwise Coupling Model for Copper-Catalyzed Radical-Radical Cross-Coupling.” Qi, Xiaotian; Zhu, Lei; Bai, Ruopeng*; Lan, Yu*, Scientific Reports 2017, 7, 43579.

 

“Computational Investigation of the Role Played by Rh(V) in the Rh(III)-Catalyzed Ortho Bromination of Arenes.” Zhang, Tao; Qi, Xiaotian; Liu, Song; Bai, Ruopeng*; Liu, Chao*; Lan, Yu*, Chem.-Eur. J.”, 2017, 11, 2690-2699.

 

“Mononuclear or Dinuclear? Mechanistic Study of the Zinc-Catalyzed Oxidative Coupling of Aldehydes and Acetylenes.” Yue, Xiaoyu, Qi, Xiaotian; Bai, Ruopeng*; Lei, Aiwen*; Lan, Yu*, Chem.-Eur. J.”, 2017, 11, 6419-6425.

 

“Ir(III)/Ir(V) or Ir(I)/Ir(III) Catalytic Cycle? Steric-Effect-Controlled Mechanism for the para-C–H Borylation of Arenes.” Zhu, Lei; Qi, Xiaotian; Li, Yingzi; Duan, Meng; Zou, Lufeng; Bai, Ruopeng*; Liu, Chao*; Lan, Yu*, Organometallics, 2017, 11, 2107-2115.

 

“Bond Dissociation Energy Controlled s-Bond Metathesis in Alkaline-Earth-Metal Hydride Catalyzed Dehydrocoupling of Amines and Boranes: A Theoretical Study.” Xu, Dongdong; Qi, Xiaotian; Duan, Meng; Yu, Zhaoyuan; Zhu, Lei; Shan, Chunhui; Yue, Xiaoyu; Bai, Ruopeng*; Lan, Yu*, Inorganic Chemistry Frontiers 2017, 4, 1813-1820.

 

“Thiolate-Palladium(IV) or Sulfonium-Palladate(0)? A Theoretical Study on the Mechanism of Palladium-Catalyzed C-S Bond Formation Reactions.” Xu, Dongdong; Qi, Xiaotian; Duan, Meng; Yu, Zhaoyuan; Zhu, Lei; Shan, Chunhui; Yue, Xiaoyu; Bai, Ruopeng*; Lan, Yu*, Organic Chemistry Frontiers 2017, 4, 943-950.

 

“The Mechanism of Alkaline Earth Metal Catalyzed Hydroboration of Carbodiimides: A Theoretical Study.” Xu, Dongdong; Shan, Chunhui; Bai, Ruopeng*; Lan, Yu*; Chinese Journal of Organic Chemistry 2017, 37, 1231-1236.

 

“Mechanistic Insights into Copper-Catalyzed Trifluoromethylation of Aryl Boronic Acids: A Theoretical Study.” He, Xiaoqian; Shan, Chunhui; Bai, Ruopeng*; Lan, Yu*; Scientia Sinica Chimica 2017, 47, 859-864.

 

“C(sp(2))-C(sp(2)) Reductive Elimination from Well-Defined Diarylgold(lll) Complexes.” Kang, Kai; Liu, Shuanshuan; Xu, Ting; Wang, Decai; Leng, Xuebing ; Bai, Ruopeng; Lan, Yu*; Shen, Qilong*; Organometallics 2017, 36, 4727-4740.

 

“Mechanism of Rhodium-Catalyzed Formyl Activation: A Computational Study”, Luo, Xiaoling#; Bai, Ruopeng#; Liu, Song; Shan, Chunhui; Chen, Changguo*; Lan, Yu*, J. Org. Chem. 2016, 81, 2320-2326.

 

“Mechanism of Synergistic Cu(II)/Cu(I)-Mediated Alkyne Coupling: Dinuclear 1,2-Reductive Elimination after Minimum Energy Crossing Point. ” Qi, Xiaotian#; Bai, Ruopeng#; Zhu, Lei; Jin, Rui; Lei, Aiwen*; Lan, Yu*, J. Org. Chem. 2016, 81, 1654-1560.

 

 “Cu(II)/Cu(I)-Synergistic Cooperation to Lead the Alkyne C-H Activation”, Bai, Ruopeng; Zhang, Guanghui; Yi, Hong; Huang, Zhiliang; Qi, Xiaotian; Liu, Chao; Miller, Jeffrey T. ; Kropf, A. Jeremy ; Bunel, Emilio E.; Lan, Yu*; Lei, Aiwen*, J. Am. Chem. Soc. 2014, 16760-16763.

 

“Revealing the Metal-like Behavior of Iodine: An Iodide-Catalysed Radical Oxidative Alkenylation”, Tang, Shan; Wu, Yong; Liao, Wenqing; Bai, Ruopeng; Liu, Chao; Lei, Aiwen*, Chem. Commun., 2014, 4496-4499.

 

“Direct Observation of Reduction of Cu(II) to Cu(I) by Terminal Alkynes” Zhang, Guanghui; Yi, Hong; Zhang, Guoting; Deng, Yi; Bai, Ruopeng; Zhang, Heng; Miller, Jeffrey T.; Kropf, Arthur J.; Bunel, Emilio E.; Lei, Aiwen*. J. Am. Chem. Soc.  2014, 924–926.

 

“Visible-Light-Mediated Decarboxylation/Oxidative Amidation of a-Keto Acids with Amines under Mild Reaction Conditions Using O2” Liu, Jie; Liu, Qiang; Yi, Hong; Qin, Chu; Bai, Ruopeng; Qi, Xiaotian; Lan, Yu*; Lei, Aiwen*. Angew. Chem. Int. Ed. 2014, 502–506.

 

“Synthesis of Pyrroles by Click Reaction: Silver-Catalyzed Cycloaddition of Terminal Alkynes with Isocyanides ” Gao, Meng; He, Chuan; Chen, Hongyi; Bai, Ruopeng; Cheng, Ben; Lei, Aiwen*. Angew. Chem. Int. Ed. 2013, 6958–6961.

 

“Easy Access to Enamides: A Mild Nickel-Catalysed Alkene Isomerization of Allylamides. ” Wang, Lu; Liu, Chao; Bai, Ruopeng; Pan, Yani; Lei, Aiwen*. Chem. Commun. 2013, 7923-7925.

 

 “Influence of 12-crown-4 on the Oxygen Electrode of Aprotic Li-O2 Battery.” Wang Xiao-Chen, Wang Ying-Ming, Liu Wei, Bai Ruopeng, Liu Yan-Fang, Xiao Li*, Lu Jun-Tao, Zhuang Lin, Acta Phys. -Chim. Sin., 2016, 32, 343-348.

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